Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (12): 188-195.doi: 10. 13475/j.fzxb.20201201008

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Research progress in photocatalytic degradation of dyes using metal-organic frameworks

LI Qing1(), CHEN Linghui1, LI Dan1, WU Zhiqiang1, ZHU Wei1, FAN Zenglu2   

  1. 1. Xi'an Key Laboratory of Textile Chemical Engineering Auxiliaries, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China
    2. Key Laboratory of Functional Textile Material and Product(Xi'an Polytechnic University), Ministry of Education, Xi'an, Shaanxi 710048, China
  • Received:2020-12-04 Revised:2021-09-10 Online:2021-12-15 Published:2021-12-29

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Abstract:

To promote the applications of metal-organic frameworks (MOFs) in dyeing wastewater treatment, research progress in using MOFs for photocatalytic degradation of dyes were reviewed. Preparation methods and high designability of their space structures were introduced, and strategies for enhancing their visible photocatalytic degradation capabilities were analyzed, including the use of organic ligands modified by chromophore to construct highly visible-light responsive MOFs. The review revealed that construction of MOFs composites with high visible-light catalytic degradation efficiency was achieved by selecting highly visible-light sensitive guest molecules and making them into the inner spaces or on the surface of MOFs for post-modification. Ideas and methods to improve the recycling ability of MOFs were discussed. The degradation performance and products of dye molecules were described and analyzed. Researches on photosensitive post-modification based on highly water stable MOFs, and exploration of the combination of this material with other traditional materials and technologies, have been suggested to be the direction for promoting the applications of MOFs in dyeing wastewater treatment.

Key words: metal-organic framework, photocatalytic degradation, dyes, visible-light responsiveness, stability, dyeing wastewater, wastewater treatment

CLC Number: 

  • TS190.2

Fig.1

Preparation methods for MOFs"

Fig.2

Deconstructing processes and topological structures of MOF-5(a) and MOF-199(b)"

Fig.3

Comparison of band gaps and light sources (UV or visible) among MOFs (a) and electron transfer pathways in dye-sensitized MOF (wide bandgap) systems (b)"

Fig.4

Terephthalic acid ligand and its modification with functional groups"

Fig.5

In-MOF composites sensitized by trichromatic photosensitizers exhibiting high efficiency and different photocatalytic degradation ability towards RB21"

Fig.6

High water stability Zr-MOF synthesized by methyl modified ligand"

Fig.7

Visible photocatalytic degradation of RB21 with highly water stable Zr-MOF composites"

Fig.8

Proposed photocatalystic degradation pathway of MB by LC-MS"

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